Hi, sorry for the delay in responding I've been a bit snowed under with project work.
Large DO concentrations are usually caused by excessive algal growth. The model doesn't do any oxygen solubility check but instead limit DO to less than 25mg/L.
The key is to use the algal limitation functions to reproduce sensible algal dynamics.
Also, you should download the latest model version, I've just found a small bug in the temperature limitation function.
Chris