I've added a fix for this in the latest download.
Note there is currently a hole in the Silica budget, all losses of Si from diatoms (respiration, excretion, mortality) are put straight into the sediments (this was done in CAEDYM as well).
CAEDYM allowed this Si to be mineralised back into the water column if the CANDI diagenesis model but I haven't implemented that in the new WQ model yet.
Chris